Solution for wastewater treatment with porous polymers. New open access manuscript in ACS Appl. Polym. Mater.

Efficiently treating wastewater contaminated with carcinogenic hexavalent chromium (Cr(VI)) has been a persistent challenge in both academic and industrial research. While ion exchange is recognised for its simplicity and effectiveness, its integration with advanced nanomaterials offers enhanced potential. The cationic porous organic polymer (POP) PTPA–PIP is a novel development poised to aid in industrial wastewater treatment.

PTPA–PIP is synthesised by converting the aromatic polyamine PTPA into its protonated form. This modification significantly increases the polymer’s hydrophilicity, enabling it to disperse uniformly in aqueous environments, which is essential for efficient water treatment applications. PTPA–PIP demonstrates the following:

High exchange capacity: PTPA–PIP exhibits a maximum adsorption capacity of 230 mg Cr2O72– per gram of polymer.

Rapid adsorption kinetics: It achieves an initial adsorption rate of 83 mg g–1 min–1, indicating ultrafast removal of contaminants.

Exceptional Selectivity: The polymer retains approximately 90% of its adsorption capacity even in the presence of a 40-fold concentration of competing anions.

Robust reusability: PTPA–PIP can be reused for at least five cycles without significant loss of performance.

This publication documents a substantial advancement in the field of wastewater treatment with porous polymers, offering a highly effective solution for addressing the challenges associated with Cr(VI) contamination.

The article can be found at the following link.

Accepted article in Macromol. Rapid Commun.

Congratulations to Maxi on having his first first-authored paper “High-Performance Dopamine-Based Supramolecular Bio-Adhesives” accepted in Macromolecular Rapid Communications!

Sutures are invasive and prone to infection, but a new class of supramolecular-based adhesives offers a better solution. In this study, dopamine-based polymers were synthesized, resulting in highly effective, non-cytotoxic adhesives with mechanical strength superior to commercial bio-adhesives like BioGlue and Tisseel. These adhesives can re-adhere, perform well in aqueous environments, and be safely removed with ethanol, demonstrating significant potential for surgical use.

“Conjugated Microporous Polymers for Catalytic CO₂ Conversion” in Advanced Science

The first publication of 2024 from the Faul Research Group, primary authored by Ulzhalgas, is an open access review covering studies demonstrating how desirable properties possessed by conjugated microporous polymers (CMPs) offer a route to sustainable and green long-term solutions.

Find a link to the manuscript here.

New review on sustainable/green methanol production

New review detailing significant advances in decarbonising methanol production with direct electrochemical techniques entitled “Can We Decarbonise Methanol Production by Direct Electrochemical CO2 Reduction?” from collaborator Alice Sheppard, currently undertaking her PhD in the Fermin Group at Bristol. Contributions from ex-Faul Group member Veronica Del Angel Hernandez.

New paper in Adv. Mater.: “Selective CO₂ Electroreduction from Tuneable Naphthalene-Based Porous Polyimide Networks”

Excited to announce Basiram and Dr. Baker‘s latest openly accessible article in Adv. Mater. entitled “Selective CO2 electroreduction from tuneable naphthalene-based porous polyimide networks” detailing exciting new metal-free materials for CO2 capture & reduction.