2018 is almost over, so all that is left to do at this stage is to thank all our collaborators, colleagues and friends (and visitors to our website!) for a great year! We wish you all a peaceful Christmas, and all the best for 2019!
Djen’s paper appeared online today on the Advanced Materials Technologies website!
A major challenge for soft electroactive devices such as dielectric elastomers is the fabrication of thin, precisely patterned, stretchable conductors. In this work, laser‐scribed graphene oxide is used to fabricate intricate, stretchable electrodes for dielectric elastomer actuators.
The method is simple, low‐cost, and green (free of organic solvents) and produces arbitrary geometries with 0.1 mm resolution.
It has been a great week for publications! Ben’s paper was recently accepted, and just appeared earlier today on the MSDE (Molecular Systems Design & Engineering) website! This study, entitled “Tipping the polaron–bipolaron balance: concentration and spin effects in doped oligo(aniline)s observed by UV-vis-NIR and TD DFT” is an invited contribution to the special themed collection “Soft Materials Nanoarchitectonics”.
We describe a robust computational protocol for modelling the molecular geometries, electronic structures and absorption spectra of oligomers of the widely-used and versatile conducting polymer, poly(aniline). By comparing experimental UV-vis-NIR and EPR spectra with TD-DFT simulations, we discovered it is possible to switch reversibly between diamagnetic and paramagnetic forms (bipolaronic and polaronic states) of oligo(aniline)s in solution simply by adjusting dopant concentrations – a finding which could reinvigorate research into conduction mechanisms in poly(aniline) and related materials, as well as allowing control of material properties and functionality.