A new study, where Charl contributed to on-going collaborative activities with former postdoc (and now professor at Donghua) Yaozu Liao, was published in Chemical Engineering Journal. This study explored modified tetraphenylmethane (TPM)-based POPs i.e. mPTPMs (synthesized via Buchwald-Hartwig cross-coupling of a tetrakis(4-bromophenyl) methane core and selected aryl diamine linkers, followed by a crosslinking alkylation strategy using diiodomethane as a crosslinker).
This new strategy offers mPTPMs with high surface areas, uniform ultramicropores where porous properties are readily controlled by the substitutions of linkers and the crosslinker. More details on the paper entitled “A crosslinking alkylation strategy to construct nitrogen-enriched tetraphenylmethane-based porous organic polymers as efficient carbon dioxide and iodine adsorbents” to follow soon!
Well done to all involved!
Congrats to Charlie and all other contributors – our paper in Macromolecules was just published! In this study, entitled “Linear and Branched Fiber-like Micelles from the Crystallization-Driven Self-Assembly of Heterobimetallic Block Copolymer Polyelectrolyte / Surfactant Complexes” we explored the solution self-assembly of a heterobimetallic diblock copolymer with a crystallizable poly(ferrocenyldimethylsilane) (PFS) core-forming block and a corona-forming segment featuring a poly(cobaltoceniumethylene) (PCE)-based polyelectrolyte/surfactant complex.
We found that key features of the one-dimensional (1D) morphologies were dependent on both the polarity of the solvent medium and temperature. Read the paper for more details – the 11th collaborative paper with the Manners group!
Charlie, former joint BCS CDT PhD student with the Manners group and now postdoc in the Seferos Group in Toronto, had another paper published from his PhD!
The study, accepted for publication in Macromolecules, explores the solution self-assembly of a heterobimetallic diblock copolymers with a crystallisable poly(ferrocenyldimethylsilane) (PFS) core-forming block and a corona-forming segment featuring a poly(cobaltoceniumethylene) (PCE) based polyelectrolyte/surfactant complex. More details to follow soon!
Congrats to Charlie, and other co-authors (Rebecca, Becs and Rob)!
Fantastic news! A paper from the Faul Research Group by Jie Chen (now back in China), Esther Townsend (BCFN), Veronica del Angel Hernandez, Pan, and colleagues from the Xi’an Jiaotong University in China appeared in Angewandte Chemie today!
The discovery of the Bristol-Xi’an Jiaotong (BXJ) approach, where we use simple inorganic salts to carefully tune N-containing conjugated microporous materials (CMPs), enables elegant synthetic control over the surface area, pore size distributions and function of N-containing CMPs. This approach enables the preparation of amorphous porous materials that start to challenge COFs and MOFs in properties and function!
Well done to all involved!!
… since our last post! Apologies! Lots have been happening since the end of March, with Charl teaching at Tsinghua, visiting Jilin and attending the UoB’s graduation ceremony (see the video here!).
In addition, Basiram has joined the group as new PhD student, and Sebastien has joined as independent research fellow, with several more visitors arriving over the summer! And, as always, someone will be leaving – this time Maciek, who will be taking up an independent academic position in Bath (congrats!).
And, finally, we hope to have some good news on some big publications very soon! More news, updates and pictures to follow soon!
Happy 2019! The year has started on a high note, with our first paper (joint with our collaborators Jiangfei Xu and Xi Zhang from the Department of Chemistry at Tsinghua) just accepted and appeared online in Chemistry Society Reviews!
Henry and Charl contributed to the tutorial review, entitled “Molecular Engineering of Polymeric Supra-amphiphiles“, where the concept of supra-amphiphiles is introduced and discussed in detail! Well done to all involved!
Djen’s paper appeared online today on the Advanced Materials Technologies website!
A major challenge for soft electroactive devices such as dielectric elastomers is the fabrication of thin, precisely patterned, stretchable conductors. In this work, laser‐scribed graphene oxide is used to fabricate intricate, stretchable electrodes for dielectric elastomer actuators.
The method is simple, low‐cost, and green (free of organic solvents) and produces arbitrary geometries with 0.1 mm resolution.